Giovani,
There are tons of example files that show you how to set a boiler. Look into the example file folder, there's a spreadsheet that details which example file has what type of system. Typical location is C:\EnergyPlusV8-2-0\ExampleFiles\ExampleFiles.xls
Also, there are HVACTemplate objects to build a boiler plant. HVACTemplate:Plan:Boiler, HVACTemplate:Plant:HotWaterLoop etc... (The Input/Output Reference can help too!)
I suggest you take a look at the example file "HVACTemplate-5ZoneBaseboardHeat.idf" which makes uses of the HVACtemplate objects to build a simple boiler plant.